This begins by roasting the whole bell peppers under a hot grill / broiler, so their skins start to char and blister. They then get sealed in a plastic bag to steam in their own heat. Once they’ve cooled enough to handle, it’s really easy to scrape off their skins.
So, set your grill / broiler to high. When it reaches temperature, lay the peppers on a baking tray, and let them roast under that high heat for 15 minutes. You’ll need to turn them a few times as they roast to get a fairly even, dark char all over their surfaces.
Once they’re darkly charred and still hot, remove them from the grill / broiler, and quickly seal them inside a plastic bag. Because they’re still hot, they’ll steam themselves in the bag. After 5 minutes of that steaming, take them from the bag, and scrape of all the charred skin.
Halve the peppers lengthwise, cut away the top stem, and deseed them. Good, peppers done.
Add the prepped peppers to your food processor together with all the other rouille ingredients except the olive oil. The oil only gets added a little later. Blitz until you a have a smooth, red paste.
Now set the processor to a low speed, and very slowly — and I mean very slowly — pour in the olive with the processor running on low. If you add the oil too quickly, you’ll find it won’t blend fully with your rouille paste. So, you should reckon on taking at least 90 seconds to slowly trickle in the oil. Take it that slowly and the oil will become completely combined with paste — excellent, rouille done.
Turn the rouille into a pretty serving dish and set it in the refrigerator while you make your bouillabaisse. You’ll find that the rouille thickens a little more during this time — and that’s just what it’s supposed to do.